Boosting oxygen evolution reaction activity with Mo incorporated NiFe-LDH electrocatalyst for efficient water electrolysis

Abstract

This work demonstrates a simple and scalable methodology for the binder-free direct growth of Mo-doped NiFe-layered double hydroxides on a nickel substrate via an electrodeposition route at room temperature. A three-dimensional (3D) nanosheet array morphology of the electrocatalyst provides immense electrochemical surface area as well as abundant catalytically active sites. Mo incorporation in the NiFe-LDH plays a crucial role in regulating the catalytic activity of oxygen evolution reaction (OER). The prepared electrocatalyst exhibited low overpotential (i.e., 230 mV) at 30 mA·cm"2 for OER in an alkaline electrolyte (i.e., 1 M KOH). Furthermore, the optimized Mo-doped NiFe-LDH electrode was used as an anodein a laboratory-scale in situ single cell test system for alkaline water electrolysis at 80 °C with a continuous flow of 30 wt% KOH, and it shows the efficient electrochemical performance with a lower cell voltage of 1.80 V at a current density of 400 mA· cm"2. In addition, an admirable long-term cell durability is also demonstrated by the cell for 24 h. This work encourages new designs and further development of electrode material for alkaline water electrolysis on a commercial scale.